Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Such failures attributed to hydrogen induced stress cracking hisc are clearly not acceptable from the perspective of safety, environmental hazard and cost. For example, in boiler tubes, hydrogen damage is caused by a corrosive reaction between steam and steel, resulting in decreased material strength and localized corrosion. This form of hydrogeninduced cracking is not related to welding. The significance of these failures has led to research aimed at defining critical conditions for hisc, to allow confident design of components in future.
Planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites. Also called hydrogen assisted cracking or hydrogen cracking, it infests either the weld zone or the heat affected zone haz. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high. Hydrogen induced cracking of subsea duplex stainless steel. Hydrogen embrittlement is often the result of unintentional introduction of hydrogen into susceptible metals during forming or finishing operations and increases cracking in the material. You can complete the definition of hydrogen induced cracking hic given by the english definition dictionary with other english dictionaries. Hydrogen embrittlement is the process by which various metals, most importantly highstrength steel, become brittle and fracture following exposure to hydrogen.
Because hydrogeninduced cracking is a weld defect that can require costly repairs and rework and possibly result in dangerous weld failures if it occurs in critical applications it is important to take steps to control and minimize the presence of hydrogen in the welding process. Hydrogen stress cracking occurs when hydrogen penetrates highstrength or hardened metal in a state of tensile stress. Hydrogen sulphide cracking is one of the important processes in the oil and gas industry as the hydrocarbons that are produced contain considerable amounts of hydrogen sulphide. Hydrogeninduced cracking hic definition hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped. Antihydrogen induced cracking material engineering. Each form can build up enough pressure to produce internal cracks.
Published by welding technology institute of australia wtia, silverwater, nsw, australia, 1999. Hic testing apparatus is provided with specially made rack to keep the samples with minimum surface contact and all the specimens can be viewed during the test period easily. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after. Hydrogen induced blistering when hydrogen is absorbed into metal and diffuses inward, it can precipitate as molecular hydrogen, at laminations, or inclusionmatrix interfaces. Planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the. Understanding weld cracking, its causes, consequencesand. Hydrogeninduced cracking hic is the stepwise internal cracks that connect adjacent hydrogen blisters on different planes in the metal, or to the metal surface. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. They can be are more sensitive to cracking during fabrication from hydrogen embrittlement delayed cracking or underbead cracking. Presentation on hydrogen induced cracking and sulfide. Hydrogen atoms produced, for example, by the corrosion reaction of iron, usually combine to form hydrogen gas molecules. Hydrogen induced cracking is a mechanical fracture caused by penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular. Several service failures attributed to such cracking have been reported. No externally applied stress is needed for the formation of hydrogeninduced cracks.
Two types of austenitic stainless steels, sus 304 and sus 316l, uniformly hydrogenprecharged to 30 mass ppm in a highpressure hydrogen environment, are subjected to tensile. Occurrences in pipelines and pressure vessels handling sour gas and oil upstream and downstream operations, gas transmission pipelines, etc. Hydrogen induced cracking hic definition hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to. Similar to thermal desorption measurement, tep is a potential method in analyzing hydrogen traps of solid solution, dislocations and irreversible traps. There are several categories of hydrogen phenomena that are localized in nature. En 10229, evaluation of resistance of steel products to hydrogen induced cracking hic. Refers to mechanical damage of metal caused by the presenceinteraction with hydrogen can be classified in to following types 1 hydrogen blistering 2 hydrogen embrittlement 3 hydrogen attack 4 decarburization hydrogen damage. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms.
Hydrogen induced cracking hic remains a prominent issue for oil and gas. Cracking results from the pressurization of trap sites by hydrogen. Sohic is a type of cracking that can easily lead to failure and needs to be mitigated. Butt welds exhibit transverse cracks while fillet welds have longitudinal ones. Stressoriented hydrogen induced cracking sohic is a common, insidious form of wet h2s cracking.
Hydrogen cracking its causes, costs and future occurrence. Hydrogen induced cracking hic there are several categories of hydrogen phenomena that are localized in nature. Also high strength structural steels which are welded are exposed to a certain hydrogen pickup which means a risk at fracture and blistering. Sohic is a special form of hic that usually occurs in the base metal, adjacent to the heataffected zone of a weld, where there are high residual stresses from welding. Hydrogen induced stress cracking of superduplex steels. Weld metal hydrogen cracking in pipeline girth welds, proc. When the crystal lattice is in contact or is saturated with atomic hydrogen, the mechanical. The fracture morphology and hydrogen induced cracking can be explained by combined hydrogen embrittlement mechanisms. Hydrogen embrittlement of austenitic stainless steels. Corrosionpedia what is hydrogeninduced cracking hic. Api rp 571 2011 termsdefinitions flashcards quizlet. This part of nace mr0175iso 15156 addresses all mechanisms of cracking that can be caused by h 2 s, including sulfide stress cracking, stress corrosion cracking, hydrogeninduced cracking and stepwise cracking, stressoriented hydrogen. A small number of duplex and superduplex stainless steel components have failed in subsea service due to hydrogen induced stress cracking hisc. Hydrogen ion definition of hydrogen ion by the free.
Hydrogen induced cracking hic is a failure mechanism resulting in sudden exposures and cracks due to growing laminations inside the base material and welds. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. The hydrogen had only a small effect on the generalyield load, but it produced cracking along planes of high shear. The phenomenon of plasticityrelated hydrogeninduced cracking can be illustrated by experimental results on a highpurity 5% ni steel tested in 0. Hydrogen induced crackinghydrogen induced cracking 2. Cold cracking is often referred to as hydrogeninduced andor heataffected zone haz cracking. Stress oriented hydrogen induced cracking sohic describes an array of cracks, aligned nearly perpendicular to the stress, that are formed by the linkup of small hic cracks in steel. Hydrogen induced cracking hic in the oil and gas industry. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure.
The related mechanism stressoriented hydrogeninduced cracking will also be. The paper looks at the problem of hydrogen cracking both in general fabrication and with particular reference to. It is characterized by the brittle fracture of a normally ductile alloy under sustained load in the presence of hydrogen. This page introduced the hydrogen induced cracking hic in ferrous and nonferrous metals including the definition and mechanism of hic, as well as the hic test in accordance with nace tm0284. However, bp and shell experience some serious cracking of duplex steel in the mid 90ties and in beginning of the century. Hydrogen induced cracking steel features, applications. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Hisc hydrogen induced stress cracking all acronyms.
Translation find a translation for hydrogen induced cracking in other languages. Broadly speaking, cold cracking occurs in the haz as the result of residual stresses from the base material restraining the weld, along with the presence of diffusible hydrogen. Hydrogeninduced craking hic, also referred to as hydrogen stress cracking or static fatigue, is a typical form of hydrogen embrittlement. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. The root cause of these failures was identified to be hydrogen induced stress cracking, hisc, where the hydrogen source was the. Hydrogen induced stress cracking hisc resistance and. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. The methane molecules create a pressure which leads. Hydrogen induced cracking hic occurs when carbon steel is exposed to hydrogen sulphide h 2 s and is the direct result of electrochemical corrosion reactions between the sour service or wet h 2 s environment. This form of hydrogen induced cracking is not related to welding. This damage is localized and requires careful scanning for detection. Atomic hydrogen entering the alloy can weaken the mechanical strength of the alloy, cause cracks and destroy the integrity of equipment or a system. Including the metallurgical and environmental conditions affecting the likelihood of hic development. Please watch the complete lecture to learn about hydrogen induced cracks, cold cracks, underbead cracks, toe cracks or haz hydrogen cracking in welding defects with their causes and preventions.
Atomic hydrogen, and not the molecule, is the smallest atom and it is small enough to diffuse readily through a metallic structure. Hydrogeninduced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants. Hydrogen induced cracking test instrument is supplied with standard size of 12l x 12w x 9h. The list of acronyms and abbreviations related to hisc hydrogen induced stress cracking. Hydrogen traps and hydrogen induced cracking in 20crmo.
Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Hydrogen induced stress cracking hisc of stainless. With hydrogen damage, multiple metal degradation processes occur due to interaction with hydrogen. When they are processed in the refineries, hydrogen sulphide gas h 2 s, which is a toxic gas is produced. Sour service is defined as oil and gas environments containing a. Hydrogen combines with carbon within the alloy and forms methane. Hydrogen induced cold cracking in a low alloy steel. Hydrogeninduced cracking hic is still a challenging issue that requires careful. Cracking is sometimes accompanied by surface blistering. Hydrogeninduced cracking is caused by nascent hydrogen atoms ho, usually produced in aqueous hydrogen sulphide h2s. Note cracking results from the pressurization of trap sites by hydrogen.
Cold cracking is particularly prevalent in thick materials, as they. For haz hydrogen cracking to occur, it is necessary for the hydrogen to migrate into the heat affected zone, which takes time. It is made up of a series of hic hydrogen induced cracking cracks that are stacked perpendicularly in the direction of through wall cracks and driven by high residual or applied stresses. Wikipedia, lexilogos, oxford, cambridge, chambers harrap, wordreference, collins lexibase dictionaries, merriam webster. Tensile strength residual or applied is required to produce sohic. Induction heating is a good option for minimizing hydrogen. The blistering damage tends to form parallel to the. Hic test, hydrogen induced cracking test, step wise. Search hydrogen induced cracking hic and thousands of other words in english definition and synonym dictionary from reverso. Definition of hydrogeninduced cracking iadc lexicon.
Hydrogen embrittlement of austenitic stainless steels has been examined with respect to deformation microstructures and lattice defects created during plastic deformation. While these metals may normally be ductile in nature, the presence of hydrogen in a corroded environment can cause it to crack. Hydrogeninduced cracking an overview sciencedirect topics. Particularly common to the oil and gas industry where the use of steel.
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